CONDUCTANCE OF LITHIUM AND SODIUM PERCHLORATES AND OF SOME QUATERNARY AMMONIUM HALIDES AND PERCHLORATES IN A PROPYLENE CARBONATE PLUS TETRAHYDROFURAN MIXTURE AT 25-DEGREES-C

被引:7
|
作者
ALNAJAR, AA [1 ]
ALAMI, KMH [1 ]
EBRAHEEM, AM [1 ]
机构
[1] UNIV BASRAH,COLL SCI,DEPT MATH,BASRAH,IRAQ
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D O I
10.1021/je00008a015
中图分类号
O414.1 [热力学];
学科分类号
摘要
The electrical conductances of lithium and sodium perchlorates and of some quaternary ammonium halides and perchlorates in propylene carbonate (PC) + tetrahydrofuran (THF) (1:1 in volume) have been measured at 25-degrees-C. The conductance data were analyzed by a minimization technique using the complete form of the Fuoss/Hsia (F/H) equation. All electrolytes were found to be anomalous in showing unusually higher molar conductances than in each solvent alone. The effect of the variation of the three parameters K(A), LAMBDA(o), and a was fully investigated.
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页码:443 / 445
页数:3
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