MEDIUM-RANGE ORDER IN POLYMERS - NONCRYSTALLINE ORDERING OF FLEXIBLE SIDE-CHAINS IN RIGID ROD POLYESTERS

被引：2
|
作者：
CERVINKA, L
机构：
[1] Institute of Physics, Czechoslovak Academy of Sciences, 16200 Prague 6
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 1992年 / 150卷 / 1-3期
关键词：
D O I：
10.1016/0022-3093(92)90110-6
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Modeling studies were performed fora rigid rod polyester with flexible side-chains in order to simulate X-ray scattering features in the medium angle scattering region, i.e., for a scattering vector from 0.2 to 1.8 angstrom-1. A typical non-crystalline peak was observed at 1.46 angstrom-1 with a shoulder at 1.75 angstrom-1 and its position and intensity could be interpreted on the basis of a dense ordering (clustering) of flexible side chains.
引用
收藏
页码：136 / 139
页数：4
相关论文
共 50 条
  • [21] ONE-DIMENSIONAL ORDER IN SMECTIC POLYMERS WITH FLEXIBLE FRAGMENTS IN SIDE-CHAINS
    TSUKRUK, VV
    SHILOV, VV
    LOKHONYA, OA
    LIPATOV, YS
    KRISTALLOGRAFIYA, 1987, 32 (01): : 157 - 167
  • [22] Fluctuation microscopy - a tool for examining medium-range order in noncrystalline systems
    Fan, L
    McNulty, I
    Paterson, D
    Treacy, MMJ
    Gibson, JM
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2005, 238 (1-4): : 196 - 199
  • [23] RIGID-ROD POLYMERS WITH POLYSILOXANE SIDE-CHAINS .2. SYNTHESIS AND CHARACTERIZATION OF AROMATIC POLYBENZOBISOXAZOLES WITH POLYSILOXANE SIDE-CHAINS AND COMPOSITE FORMATION WITH POLYSILOXANE MATRICES
    SAKAKIBARA, A
    ITOH, M
    MITA, I
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (08) : 1293 - 1303
  • [24] RIGID RODS WITH FLEXIBLE SIDE-CHAINS - A ROUTE TO MOLECULAR REINFORCEMENT
    HEITZ, T
    ROHRBACH, P
    HOCKER, H
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1989, 190 (12): : 3295 - 3316
  • [25] A STUDY OF SIDE-CHAIN ORDERING IN ORIENTED RIGID-ROD POLYESTERS
    CERVINKA, L
    POLYMER, 1994, 35 (24) : 5225 - 5234
  • [26] Rigid-rod polyesters with flexible side chains .6. Appearance of hexagonal columnar phase as a consequence of microsegregation of aromatic main chains and aliphatic side chains
    Watanabe, J
    Sekine, N
    Nematsu, T
    Sone, M
    Kricheldorf, HR
    MACROMOLECULES, 1996, 29 (13) : 4816 - 4818
  • [27] RIGID ROD POLYMERS WITH FLEXIBLE SIDE-CHAINS - SYNTHESIS, STRUCTURE AND PHASE-BEHAVIOR OF POLY(3-N-ALKYL-4-OXYBENZOATE)S
    STERN, R
    BALLAUFF, M
    LIESER, G
    WEGNER, G
    POLYMER, 1991, 32 (11) : 2096 - 2105
  • [28] DIPOLE-MOMENTS OF VINYL-POLYMERS WITH FLEXIBLE SIDE-CHAINS
    ABE, A
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER SYMPOSIUM, 1976, (54): : 135 - 144
  • [29] RIGID ROD POLYMERS HAVING FLEXIBLE SIDE-CHAINS .1. THERMOTROPIC POLY(1,4-PHENYLENE 2,5-DIALKOXYTEREPHTHALATE)S
    BALLAUFF, M
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1986, 7 (06): : 407 - 414
  • [30] RIGID-ROD POLYESTERS WITH FLEXIBLE SIDE-CHAINS .4. THERMOTROPIC BEHAVIOR AND PHASE STRUCTURES IN POLYESTERS BASED ON 1,4-DIALKYL ESTERS OF PYROMELLITIC ACID AND 4,4'-BIPHENOL
    WATANABE, J
    HARKNESS, BR
    SONE, M
    ICHIMURA, H
    MACROMOLECULES, 1994, 27 (02) : 507 - 512
12345