DIRECT OBSERVATION OF THE CENTRAL ATOM IN [C(AU[P(C6H5)2(P-C6H4NME2)])6](BF4)2 BY C-13 NMR-SPECTROSCOPY

被引：39
|
作者：
SCHMIDBAUR, H
BRACHTHAUSER, B
STEIGELMANN, O
机构：
[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, W-8046
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期
关键词：
D O I：
10.1002/anie.199114881
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of the title compound in which the interstitial C atoms are mainly C-13 isotopes makes the proof of these octahedral hypercoordinated atoms possible. The septet multiplicity and the coupling constants confirm the postulated surroundings and agree with the expectations regarding bonding. The chemical shift-delta(C-13) = 137.27 is more difficult to understand. Relativistic effects must be taken into account in the crucial theoretical calculations.
引用
收藏
页码：1488 / 1490
页数：3
相关论文
共 50 条
  • [41] Sonochemical synthesis and characterization of Ni(C4H6N2)6(PF6)2, Fe(C4H6N2)6(BF4)2, and Ni(C4H6N2)6(BF4)2 in 1-butyl-3-methylimidazole with hexafluorophosphate and tetrafluoroborate
    Jacob, DS
    Makhluf, S
    Brukental, I
    Lavi, R
    Solovyov, LA
    Felner, I
    Nowik, I
    Persky, R
    Gottlieb, HE
    Gedanken, A
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (13) : 2669 - 2677
  • [42] Crystal structure of azido-(N,N-dimethylbenzylamine-C2 [1,3-bis(diphenylphosphino)propane-P,P′)]palladium(II), {Pd(C6H4CH2NMe2-C2)(N3)[(C6H5)2P(CH2)3P(C6H5)2-P,P′]}
    de Almeida, ET
    Santana, AM
    Netto, AVD
    Mauro, AE
    Santos, MP
    Santos, RHA
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (03): : 366 - 368
  • [43] CRYSTAL AND MOLECULAR-STRUCTURES OF [(C6H5)P4]2FE(S2C4O2)2 AND [(C6H5)P4]2FE(SC6H5)4, A STRUCTURAL ANALOG OF REDUCED RUBREDOXIN
    COUCOUVANIS, D
    SWENSON, D
    BAENZIGER, NC
    HOLAH, DG
    KOSTIKAS, A
    SIMOPOULOS, A
    PETROULEAS, V
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) : 5721 - 5723
  • [44] SPECTROSCOPY OF JET-COOLED P-C6H4CL2 AND P-C6H4CL2.AR
    SANDS, WD
    MOORE, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 125 - PHYS
  • [45] STRUCTURE OF [IR(ETA-11-C5ME4C3H6C6H2ME3)](BF4)2.MEOH
    LUMME, PO
    TURPEINEN, U
    KAGANOVICH, VS
    KUDINOV, AR
    RYBINSKAYA, MI
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 559 - 561
  • [46] Transition metal complexes containing P(C6H5)(C6H4Cl-2)2.: The effect of added Lewis bases as a probe for substitution reactions occurring in ambient temperature Suzuki couplings catalyzed by Pd/P(C6H5)(C6H4Cl-2)2
    Stone, JJ
    Stockland, RA
    Rath, NP
    INORGANICA CHIMICA ACTA, 2003, 342 : 236 - 240
  • [47] SYNTHESIS, STRUCTURE AND PROPERTIES OF THE ADDITIVE COMPOUND [(C6H5)4P]2[FECL4][C6H6] 1/2 [H2NSCCSNH2]
    XU, JQ
    QIAN, JS
    WEI, Q
    YANG, GD
    CHINESE SCIENCE BULLETIN, 1989, 34 (22): : 1866 - 1870
  • [48] SYNTHESIS, STRUCTURE AND PROPERTIES OF THE ADDITIVE COMPOUND [(C6H5)4P]2[FeCl4][C6H6]1/2[H2NSCCSNH2]
    徐吉庆
    千吉松
    魏诠
    杨光弟
    ChineseScienceBulletin, 1989, (22) : 1866 - 1870
  • [49] SYNTHESIS AND THERMAL DECOMPOSITION OF PEROXIDES (C6H5)4SBOOSI(C6H5)3 AND (C6H5)4SBOOGE(C6H5)3
    RAZUVAEV, GA
    ZINOVEVA, TI
    BRILKINA, TG
    DOKLADY AKADEMII NAUK SSSR, 1969, 188 (04): : 830 - &
  • [50] Living polymerization of phenylacetylene by isolated rhodium complexes, Rh[C(C6H5)=C(C6H5)2](nbd)(4-XC6H4)3P (X = F, Cl)
    Miyake, M
    Misumi, Y
    Masuda, T
    MACROMOLECULES, 2000, 33 (18) : 6636 - 6639
12345