A NEW STEREOSELECTIVE METHOD FOR SYNTHESIS OF OPTICALLY-ACTIVE BETA-ALKYLHOMOALLYL ALCOHOLS AND GAMMA,DELTA-EPOXY-BETA-ALKYL ALCOHOLS

被引：5

作者：

ITO, T ^{[1
]}

YAMAKAWA, I ^{[1
]}

OKAMOTO, S ^{[1
]}

KOBAYASHI, Y ^{[1
]}

SATO, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,MEGURO KU,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(00)92631-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and general method for synthesis of optically active beta-alkylhomoallyl alcohols and gamma, delta-epoxy-beta-alkyl secondary alcohols starting with DELTA-alpha,beta-butenolides having trimethylsilyl and phenylthio group at alpha-position, respectively, has been developed.

引用

页码：371 / 374

页数：4

共 50 条

[31] SYNTHESIS OF OPTICALLY-ACTIVE BETA-KETO-GAMMA-BUTYROLACTONES HAVING A TRIFLUOROMETHYL GROUP
KITAZUME, T
JOURNAL OF FLUORINE CHEMISTRY, 1987, 35 (02) : 287 - 294
[32] GAS CHROMATOGRAPHIC RESOLUTION OF OPTICALLY ACTIVE ALCOHOLS AS 3 BETA-ACETOXY-DELTA5-ETIENATES
ANDERS, MW
COOPER, MJ
ANALYTICAL CHEMISTRY, 1971, 43 (08) : 1093 - &
[33] A NEW SYNTHESIS OF OPTICALLY-ACTIVE BETA-MERCAPTOCARBOXYLIC ACID-ESTERS
SHONO, T
MATSUMURA, Y
FUJITA, T
TETRAHEDRON LETTERS, 1991, 32 (46) : 6723 - 6726
[34] STEREOSELECTIVE PICTET-SPENGLER REACTIONS - APPLICATION TO THE SYNTHESIS OF OPTICALLY-ACTIVE TETRAHYDRO BETA-CARBOLINES
REDDY, MS
COOK, JM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 312 - ORGN
[35] SYNTHESIS OF OPTICALLY-ACTIVE (E)-GAMMA-HYDROXY-ALPHA,BETA-UNSATURATED NITRILES
KANG, SK
LEE, DH
KIM, YS
KANG, SC
SYNTHETIC COMMUNICATIONS, 1992, 22 (08) : 1109 - 1113
[36] GENERAL METHOD FOR SYNTHESIS OF ALPHA-AMINO-BETA,GAMMA-ACETYLENIC ALCOHOLS
EPSZTEIN, R
MERCIER, F
SYNTHESIS-STUTTGART, 1977, (03): : 183 - 184
[37] STEREOSELECTIVE SYNTHESIS OF ALCOHOLS .15. STEREOSELECTIVE SYNTHESIS OF ALPHA-ALKYL-ALPHA,BETA-DIHYDROXYCARBOXYLIC ESTER DERIVATIVES - SYNTHESIS OF (+)-VIRIDIFLORIC ACID
LADNER, W
CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (10): : 3413 - 3426
[38] SYNTHESIS OF OPTICALLY-ACTIVE ALPHA-TRIMETHYLSILYL DELTA(ALPHA,BETA)BUTENOLIDES AND THEIR CONVERSION INTO VARIOUS BUTENOLIDES AND SATURATED GAMMA-LACTONES
ITO, T
OKAMOTO, S
SATO, F
TETRAHEDRON LETTERS, 1990, 31 (44) : 6399 - 6402
[39] SMI2-INDUCED HIGHLY REGIOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY ESTERS AND GAMMA,DELTA-EPOXY-ALPHA,BETA-UNSATURATED ESTERS - AN EFFICIENT ROUTE TO OPTICALLY-ACTIVE BETA-HYDROXY AND DELTA-HYDROXY ESTERS
OTSUBO, K
INANAGA, J
YAMAGUCHI, M
TETRAHEDRON LETTERS, 1987, 28 (38) : 4437 - 4440
[40] SELECTIVE OXIDATION OF BETA-ALLENIC ALCOHOLS - NEW METHOD FOR PREPARING GAMMA LACTONES
BERTRAND, M
DULCERE, JP
GIL, G
GRIMALDI, J
SYLVESTREPANTHET, P
TETRAHEDRON LETTERS, 1976, (37) : 3305 - 3308

← 1 2 3 4 5 →