THE STANDARD MOLAR ENTHALPY OF FORMATION OF HFMO2O8

被引：3
|
作者：
BHARADWAJ, SR [1 ]
SAMANT, MS [1 ]
MISHRA, R [1 ]
DHARWADKAR, SR [1 ]
SAVANT, SS [1 ]
KALYANARAMAN, R [1 ]
机构：
[1] BHABHA ATOM RES CTR,DIV ANALYT CHEM,BOMBAY 400085,MAHARASHTRA,INDIA
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1995年 / 230卷 / 01期
关键词：
FREE ENERGY OF FORMATION; MOLYBDATE; ENTHALPY OF FORMATION; TELLURATE;
D O I：
10.1016/0925-8388(95)01910-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The molar enthalpies of solution of HfMo2Og, Mo and HfF4 in (10 mol HF(aq) + 4.41 mol H2O2(aq)) dm(-3) have been measured using an isoperibol type calorimeter. From these results and other auxiliary data, the standard molar enthalpy of formation of HfMo2O8(s) has been calculated to be Delta(f)H(m)(298.15 K) = -2605.8 +/- 5.9 kJ mol(-1). This value of enthalpy of formation of HfMo2O8 is consistent with the second law enthalpy of formation of HfMo2O8 determined in this laboratory by transpiration technique.
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收藏
页码：13 / 15
页数：3
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