[AUCO3RU(C8H11P)(C18H15P)(CO)11].1/2CH2CL2

被引：4

作者：

KAKKONEN, HJ ^{[1
]}

AHLGREN, M ^{[1
]}

PAKKANEN, TA ^{[1
]}

PURSIAINEN, J ^{[1
]}

机构：

[1] UNIV OULU,DEPT CHEM,SF-90570 OULU,FINLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193009710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

HRuCo3(CO)11PMe2Ph reacts with AuPPh3Cl giving a substitution product, penta-mu-carbonyl-1:2kappa2C;1:3kappa2C;2:3kappa2C;2:4kappa2C;3:4kappa2C-hexacarbonyl-1kappa2C,-2kappaC,3kappaC,4kappa2C-dimethylphenylphosphine-1kappaP-tri-phenylphosphine-5kappaP-tricobaltgoldruthenium(3 Au-Co)(3 Co-Co)(3 Co-Ru), where the [AuPPh3]+ moiety shields the basal Co3 face. The PMe2Ph ligand changes coordination from an axial site of the basal Co3 plane to the apical Ru atom.

引用

页码：528 / 530

页数：3

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