[AUCO3RU(C8H11P)(C18H15P)(CO)11].1/2CH2CL2

被引：4
|
作者：
KAKKONEN, HJ [1 ]
AHLGREN, M [1 ]
PAKKANEN, TA [1 ]
PURSIAINEN, J [1 ]
机构：
[1] UNIV OULU,DEPT CHEM,SF-90570 OULU,FINLAND
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S0108270193009710
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
HRuCo3(CO)11PMe2Ph reacts with AuPPh3Cl giving a substitution product, penta-mu-carbonyl-1:2kappa2C;1:3kappa2C;2:3kappa2C;2:4kappa2C;3:4kappa2C-hexacarbonyl-1kappa2C,-2kappaC,3kappaC,4kappa2C-dimethylphenylphosphine-1kappaP-tri-phenylphosphine-5kappaP-tricobaltgoldruthenium(3 Au-Co)(3 Co-Co)(3 Co-Ru), where the [AuPPh3]+ moiety shields the basal Co3 face. The PMe2Ph ligand changes coordination from an axial site of the basal Co3 plane to the apical Ru atom.
引用
收藏
页码：528 / 530
页数：3
相关论文
共 50 条
  • [1] [RECL3(C8H11P)2(C7H11N)2]CENTER-DOT-C6H4CL2
    MASCIOCCHI, N
    MORET, M
    ARDIZZOIA, GA
    LAMONICA, G
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 201 - 203
  • [2] STRUCTURES OF [COCL(C18H15P)3] AND [NICL(C18H15P)3].C7H8
    CASSIDY, JM
    WHITMIRE, KH
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 2094 - 2098
  • [3] BIS(DIMETHYLGLYOXIMATO)PHENYLACETYLIDO)-(TRIPHENYLPHOSPHINE)RHODIUM(III) DICHLOROMETHANE, [RH(C4H7N2O2)2-(C8H5)(C18H15P)].CH2CL2
    DUNAJJURCO, M
    KETTMANN, V
    STEINBORN, D
    LUDWIG, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 210 - 213
  • [4] Bis(dimethylglyoximato)(phenylacetylido)(triphenylphosphine)rhodium(II I) dichloromethane, [Rh(C4H7N2O2)2 (C8H5)(C18H15P)]CH2Cl2
    Acta Crystallogr Sect C Cryst Struct Commun, pt 2 (210):
  • [5] TRIBROMOTRIS(DIMETHYLPHENYLPHOSPHINE)RHODIUM RHBR3(C8H11P)3
    ENGLISH, RB
    CRYSTAL STRUCTURE COMMUNICATIONS, 1979, 8 (01): : 167 - 172
  • [6] ISOMERIZATION OF RUCL2C6H5P(CH2CH2CH2P(C6H11)2)2) IN SOLUTION
    JIA, GC
    LEE, IM
    MEEK, DW
    GALLUCCI, JC
    INORGANICA CHIMICA ACTA, 1990, 177 (01) : 81 - 88
  • [7] Crystal structure of bis(triphenylphospine-κP)-dichloropalladium(II) - acetonitrile (1:1), [PdCl2(C18H15P)2] • CH3CN
    Cui, Li-Na
    Li, Zhong-Feng
    Wen, Jin
    Jiang, Yu-Han
    Jin, Qiong-Hua
    Gong, Hui-Li
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (04): : 591 - 592
  • [8] IRIDIUM(III) HYDRIDES OF THE CHELATING PHOSPHINES CYTTP (C6H5P[CH2CH2CH2P-(C6H11)2]2) AND TTP (C6H5P[CH2CH2CH2P(C6H5)2]2)
    PRENGEL, C
    SOCOL, S
    MEEK, DW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 238 - INOR
  • [9] The first double oxidative addition of CH2Cl2 to a metal complex: facile synthesis of [Ru(CH2)Cl-2{P(C6H11)(3)}(2)]
    Olivan, M
    Caulton, KG
    CHEMICAL COMMUNICATIONS, 1997, (18) : 1733 - 1734
  • [10] Synthesis and reactions of the cyclooctadienylmolybdenum complexes[MoBr(CO)2(NCMe)2(η3-C8H11)] (η3-C8H11=1-3-η:4,5-C8H11 or 1-3-η:5,6-C8H11)
    Spencer, DM
    Beddoes, RL
    Dissanayake, RK
    Helliwell, M
    Whiteley, MW
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 1009 - 1019
12345