DIRHODIUM TETRAACETATE-CATALYZED DECOMPOSITION OF BETA,GAMMA-UNSATURATED DIAZO KETONES - A NEW ENTRY TO VINYLOGOUS WOLFF REARRANGEMENT

被引：0

作者：

CECCHERELLI, P ^{[1
]}

CURINI, M ^{[1
]}

MARCOTULLIO, MC ^{[1
]}

ROSATI, O ^{[1
]}

机构：

[1] UNIV PERUGIA,FAC FARM,IST CHIM ORGAN,VIA LICEO,I-06100 PERUGIA,ITALY

来源：

GAZZETTA CHIMICA ITALIANA | 1994年 / 124卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dirhodium tetraacetate-catalyzed decomposition of the beta, gamma-unsaturated diazo ketones 1-4, in the presence of methanol, leads to gamma,delta-unsaturated esters 5-8 via zwitterionic intermediates (i.e., d).

引用

页码：177 / 179

页数：3

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