INTRAMOLECULAR HYDROGEN-BONDS IN QUADRICYCLANE DERIVATIVES

被引：0
|
作者：
IRNGARTINGER, H
JAHN, R
机构：
来源：
CROATICA CHEMICA ACTA | 1991年 / 64卷 / 03期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two bulky hydroxy-isopropyl substituents on the quadricyclane 2 generate a compression of the intramolecular hydrogen bond (014...015 2.687 angstrom) and a lengthening of the C1-C5 bond (1.573 angstrom) of the four membered ring. The corresponding values of the bis(hydroxymethyl) derivative 1 are 010...011 2.799 angstrom and C1-C5 1.546 angstrom), respectively.
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页码：289 / 294
页数：6
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