TRANSITION-METAL HETEROALLENE COMPLEXES .25. REACTIONS OF KETENE IMINE WITH RU3(CO)12

被引：8

作者：

ZIEGLER, W ^{[1
]}

BEHRENS, U ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80076-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N-Tolyl-diphenylketenimine (Ph2C=C=NAr, Ar = P-tolyl; C21H17N) (1) reacts with Ru3(CO)12 in boling toluene to yield a trinuclear and a dinuclear complex of formula Ru3(CO)8(C21H17N) (4) and Ru2(CO)6(C21H17N) (5). Reaction of 4 with CO leads to Ru(CO)5 and complex 5. PMe3 and PPh3 react both with 4 and 5 to give the dinuclear phosphane-substituted complexes Ru2(CO)5(PMe3)-(C21H17N) (6) and Ru2(CO)4(PPh3)2(C21H17N) (7), respectively. The structures of the compounds 4, 6 and 7 were determined by X-ray diffraction.

引用

页码：379 / 393

页数：15

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