CO2(CO)8-CATALYZED RING-OPENING CARBONYLATION OF CYCLIC ETHERS USING N-SILYLAMINES

被引：19
|
作者：
WATANABE, Y
NISHIYAMA, K
ZHANG, K
OKUDA, F
KONDO, T
TSUJI, Y
机构：
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 03期
关键词：
D O I：
10.1246/bcsj.67.879
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Co2(CO)8-catalyzed ring-opening carbonylation of oxiranes and oxetane smoothly proceeds with high regioselectivity under 1 atm of carbon monoxide at room temperature to give the corresponding beta- and gamma-siloxy amides in high yields, respectively. [(R3Si)2NR1R2]+[Co-(CO)4]- is thought to be an active catalyst species and directs the high regioselectivity of the carbonylation.
引用
收藏
页码：879 / 882
页数：4
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