N,N,N ',N '-Tetrabenzyl-N ''-(2,6-difluoro-benzoyl)phosphoric triamide

被引:0
|
作者
Shabari, Akbar Raissi [1 ]
Pourayoubi, Mehrdad [2 ]
Tarahhomi, Atekeh [2 ]
Rheingold, Arnold L. [3 ]
Golen, James A. [3 ]
机构
[1] Islamic Azad Univ, Fac Chem, North Tehran Branch, Tehran, Iran
[2] Ferdowsi Univ Mashhad, Dept Chem, Mashhad, Iran
[3] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA
关键词
D O I
10.1107/S1600536812042481
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the C(O)NHP(O) fragment of the title compound, C35H32F2N3O2P, the P-N bond is longer and the O-P-N angle is contracted compared with the other two P-N bonds and O-P-N angles. The P atom adopts a distorted tetrahedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzylamido groups show sp(2) character with a slight deviation from planarity. In the crystal, pairs of N-H center dot center dot center dot O(P) hydrogen bonds form inversion dimers.
引用
收藏
页码:O3186 / +
页数:10
相关论文
共 50 条
  • [21] N-(2-Fluorobenzoyl)-N′,N"-bis(4-methylphenyl)phosphoric triamide
    Pourayoubi, Mehrdad
    Tarahhomi, Atekeh
    Rheingold, Arnold L.
    Golen, James A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O934 - U1049
  • [22] N,N '-Dibenzyl-N ''-(2-chloro-2,2difluoroacetyl)phosphoric triamide
    Pourayoubi, Mehrdad
    Keikha, Mojtaba
    Jasinski, Jerry P.
    Keeley, Amanda C.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3009 - +
  • [23] N,N '-Bis(4-methylphenyl)-N ''-(2,2,2-trichloroacetyl)phosphoric triamide
    Shabari, Akbar Raissi
    Pourayoubi, Mehrdad
    Fadaei, Hassan
    Necas, Marek
    Babiak, Michal
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1813 - +
  • [24] The interaction of N,N,N′,N′-tetramethylphosphoric triamide with chloral:: Phosphorus-nitrogen fission products and the X-ray crystal structure of N,N,N′,N′-tetramethyl-N"-(2,2,2-trichloro-1-dimethylaminoethyl)phosphoric triamide
    Hudson, HR
    McPartlin, M
    MaVrommatis, CN
    Pianka, M
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 127 : 39 - 48
  • [25] N-Benzoyl-N′-(2,6-dimethylphenyl)thiourea
    Usman, A
    Razak, IA
    Satar, S
    Kadir, MA
    Yamin, BM
    Fun, HK
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : O656 - O658
  • [26] Synthesis, structures, EPR and ENDOR investigations on transition metal complexes of N,N-diisobutyl-N′-(2,6-difluoro)benzoyl selenourea
    Kampf, M
    Richter, R
    Griebel, J
    Weller, A
    Kirmse, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (04): : 698 - 708
  • [27] N,N′-Dibenzyl-N"-(2-chloroacetyl)-N,N′-dimethylphosphoric triamide
    Pourayoubi, Mehrdad
    Keikha, Mojtaba
    Necas, Marek
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2439 - U1219
  • [28] N,N-Dimethyl-N′,N"-diphenylphosphoric triamide
    Pourayoubi, Mehrdad
    Yousefi, Mohammad
    Eslami, Farnaz
    Rheingold, Arnold L.
    Chen, Chao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3220 - U1885
  • [29] N,N′-Dicyclohexyl-N",N"-dimethylphosphoric triamide
    Sabbaghi, Fahimeh
    Pourayoubi, Mehrdad
    Ahmadabad, Fatemeh Karimi
    Azarkamanzad, Zahra
    Valmoozi, Ali Asghar Ebrahimi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O502 - U1840
  • [30] N,N′-Dicyclopentyl-N",N"-dimethylphosphoric triamide
    Shabari, Akbar Raissi
    Pourayoubi, Mehrdad
    Ghoreishi, Farnaz
    Vahdani, Banafsheh
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3401 - U1403