REINVESTIGATION OF THE ELECTRONIC-SPECTRUM OF THE PHENYLNITRENE RADICAL

被引：26
|
作者：
CULLIN, DW [1 ]
YU, L [1 ]
WILLIAMSON, JM [1 ]
PLATZ, MS [1 ]
MILLER, TA [1 ]
机构：
[1] OHIO STATE UNIV,DEPT CHEM,LASER SPECTR FACIL,120 W 18TH AVE,COLUMBUS,OH 43210
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期
关键词：
D O I：
10.1021/j100372a010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The origin band of the electronic transition long attributed to gaseous triplet phenylnitrene has been investigated by using a very high resolution pulsed laser to interrogate molecules cooled in a supersonic jet. The observed rotational and spin structure of this band is inconsistent with simple ideas of triplet phenylnitrene's structure and spectra. Details of these inconsistencies are presented. A possible alternative carrier for the spectrum is presented. © 1990 American Chemical Society.
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收藏
页码：3387 / 3391
页数：5
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