Novel crystal modification of fac-triamminetrinitrorhodium(III) — β-fac-[Rh(NO2)3(NH3)3]

被引：0

作者：

S. A. Gromilov

S. V. Korenev

I. A. Baidina

S. P. Khranenko

机构：

[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division

来源：

Journal of Structural Chemistry | 2005年 / 46卷

关键词：

rhodium; powder X-ray diffraction; single crystal X-ray diffraction; crystal chemistry;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The paper describes the preparation techniques for β-fac-[Rh(NO2)3(NH3)3]. The complex crystallizes as colorless prisms belonging to the monoclinic crystal system. Crystal data: a = 6.6338(2) Å, b = 11.0627(3) Å, c = 11.5314(3) Å; β = 96.608(1)°, V = 840.64(4) Å3, space group P21/n, Z = 4, dcalc = 2.308 g/cm3. The structure is molecular and contains neutral complex molecules having the fac configuration. Crystal chemical analysis of the complex in comparison to α-fac-[Rh(NO2)3(NH3)3] is performed.

引用

页码：719 / 724

页数：5

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