Inclusion of tetramethylpyrazine in channels of the organic zeolite 2,4,6-tris(4-bromophenoxy)-1,3,5-triazine

被引：0
|
作者：
Gaëtan Couderc
Michel Bonin
Gaël Labat
Ricarda Berger
Jürg Hulliger
机构：
[1] University of Berne,Department of Chemistry and Biochemistry
来源：
Journal of Inclusion Phenomena and Macrocyclic Chemistry | 2008年 / 61卷
关键词：
Host–guest systems; Inclusion compounds; Organic zeolites;
D O I：
暂无
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学科分类号：
摘要：
2,4,6-tris(4-bromophenoxy)-1,3,5-triazine (BrPOT) features a channel size (11–12 Å) allowing the inclusion of large guest molecules such as tetramethylpyrazine (TMPZ). TMPZ forms π-stacks (d: 3.5 Å) along channels of BrPOT and shows rotational disorder for methyl positions. Co-inclusions of I2 resulted in a doped state where I2 molecules are oriented perpendicular to the channel axis with positional disorder as well. The particular orientation of I2 molecules is evident from the observed dichroism.
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页码：377 / 379
页数：2
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