The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys

被引：0
|
作者：
Yu. Plevachuk
A. Yakymovych
S. Fürtauer
H. Ipser
H. Flandorfer
机构：
[1] Ivan Franko National University,Department of Metal Physics
[2] University of Vienna,Department of Inorganic Chemistry (Materials Chemistry)
来源：
Journal of Phase Equilibria and Diffusion | 2014年 / 35卷
关键词：
calorimetry; enthalpy of mixing; metallic alloys; ternary;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections xNi/xSn ≈ 1:9, xNi/xSn ≈ 1:6 at 1073 K and along two sections xSn/xZn ≈ 9:1, xSn/xZn ≈ 4:1 at 873 K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. −20000 J mol-1 corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000 J mol-1 is equal to the maximum in the binary Sn-Zn system.
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页码：359 / 368
页数：9
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