Asymmetric spiroacetalization catalysed by confined Brønsted acids

被引:0
|
作者
Ilija Čorić
Benjamin List
机构
[1] Max-Planck-Institut für Kohlenforschung,
[2] Kaiser-Wilhelm-Platz 1,undefined
[3] 45470 Mülheim an der Ruhr,undefined
[4] Germany,undefined
来源
Nature | 2012年 / 483卷
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摘要
Spiroacetals are found in a broad range of biologically active compounds, including small insect pheromones and more complex macrocycles; a confined imidodiphosphoric-acid catalyst is now reported that is able to facilitate the stereoselective synthesis of small, unfunctionalized spiroacetals.
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页码:315 / 319
页数:4
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