Solvent Effect on the Partial Molar Volume and the Enthalpy of Solution of Gallium Chloride

被引：0
|
作者：
S. V. Kiselev
E. A. Kashaeva
A. I. Konovalov
机构：
[1] Kazan State University,Butlerov Research Chemical Institute
[2] Kazan,undefined
来源：
Russian Journal of General Chemistry | 2001年 / 71卷
关键词：
Acetate; Chloride; Ethyl; Enthalpy; Benzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Partial molar volumes and heats of solution were determined for gallium chloride in benzene, toluene, o-xylene, mesitylene, 1,2-dichloroethane, ethyl acetate, acetonitrile, and 1,4-dioxane. A proportionality in changes in these characteristics is observed for weak π,ν-type complexes in alkylbenzene medium. The partial molar volumes of strong n,ν-type complexes approach a limiting value.
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页码：1203 / 1207
页数：4
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