Spectrofluorimetric determination of phenyl-β-naphthylamine used as rubber antioxidant

被引:0
|
作者
Zenovia Moldovan
Cristina Stoica
Mihaela Hillebrand
Laurenţia Alexandrescu
Gabriela Macovescu
机构
[1] University of Bucharest,Faculty of Chemistry
[2] Research Development National Institute for Textile and Leather,Division Leather and Footwear Research Institute
来源
关键词
Phenyl-; -naphthylamine; Antioxidant; Polymer additive; Fluorimetry;
D O I
暂无
中图分类号
学科分类号
摘要
Phenyl-β-naphthylamine (PBN) used as rubber antioxidant was found to have native fluorescence. A spectrofluorimetric method for determination of PBN in multicomponent mixtures of polymer additives is described. The apparent excitation and fluorescence wavelengths used are 348 and 413.5 nm, respectively. Maximum fluorescence intensity is obtained by irradiating PBN dissolved in ethanol, at room temperature. The fluorescence varies linearly with the concentration of PBN in the range of 0.04–4 μg mL−1. The accuracy and precision of the method are reported.
引用
收藏
页码:1381 / 1386
页数:5
相关论文
共 50 条
  • [41] SPECTROFLUORIMETRIC DETERMINATION OF CO(II) TRACES WITH HYDRAZONES OF PHENYL-2-PYRIDYLKETONE AND DIPYRIDYLGLYOXAL - NON-KINETIC AND KINETIC METHODS
    GRASES, F
    GARCIASANCHEZ, F
    VALCARCEL, M
    ANALES DE QUIMICA SERIE B-QUIMICA INORGANICA Y QUIMICA ANALYTICA, 1980, 76 (03): : 402 - 407
  • [42] Green micellar spectrofluorimetric determination of α-mangostin found in herbal products as antioxidant and other biological activities beneficial to human health
    Salem, Hesham
    Mazen, Dina Z. Z.
    Emad, Nadeen
    Hassan, Hossam
    Omran, Bahaa
    Abdelmajed, Mahmoud A. A.
    LUMINESCENCE, 2023, 38 (06) : 672 - 679
  • [43] Azo-8-hydroxyquinoline dyes: The synthesis, characterizations and determination of tautomeric properties of some new phenyl- and heteroarylazo-8-hydroxyquinolines
    Saylam, Aytul
    Seferoglu, Zeynel
    Ertan, Nermin
    JOURNAL OF MOLECULAR LIQUIDS, 2014, 195 : 267 - 276
  • [44] Spectrofluorimetric first derivative synchronous approach for determination of olanzapine and samidorphan used for treatment of schizophrenia in pharmaceutical formulations and human plasma
    Salem, Hesham
    Samir, Ebtihal
    Mazen, Dina Z.
    Madian, Hoda
    Elkhateeb, Alshimaa E.
    Elaraby, Manar
    Rasekh, Manar I.
    Gamal, Aliaa
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2022, 274
  • [45] Simultaneous determination of phenyl- and sulfonylurea herbicides in water by solid-phase extraction and liquid chromatography with UV diode array or mass spectrometric detection
    Carabias-Martínez, R
    Rodríguez-Gonzalo, E
    Herrero-Hernández, E
    Hernández-Méndez, J
    ANALYTICA CHIMICA ACTA, 2004, 517 (1-2) : 71 - 79
  • [46] Test Determination of Mechanical Characteristics for Rubber Plates used at K Railway Fastening System
    Sebesan, Ioan
    Paraschiv, Gigel
    Zaharia, Nicusor Laurentiu
    MATERIALE PLASTICE, 2012, 49 (03) : 192 - 195
  • [47] Direct determination of methamphetamine enantiomers in urine by liquid chromatography with a strong cation-exchange precolumn and phenyl-β-cyclodextrin-bonded semi-microcolumn
    Makino, Y
    Suzuki, A
    Ogawa, T
    Shirota, O
    JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 1999, 729 (1-2): : 97 - 101
  • [48] CHEMICAL PROCESSES STATISTICAL CONTROL DIAGRAMS BASED ON NUCLEAR TECHNIQUES - DETERMINATION OF THE TRI-N(NONYL-PHENYL) PHOSPHITE ANTIOXIDANT SEPARATION IN THE BUTADIENE ALPHA-METHYLSTYRENE RUBBER
    STOICA, M
    POPESCU, M
    REVISTA DE CHIMIE, 1993, 44 (08): : 762 - 766
  • [49] Direct determination of methamphetamine enantiomers in urine by liquid chromatography with a strong cation-exchange precolumn and phenyl-β-cyclodextrin-bonded semi-microcolumn
    Makino, Yukiko
    Suzuki, Ayako
    Ogawa, Takashi
    Shirota, Osamu
    Journal of Chromatography B, 1999, 729 (1-2): : 97 - 101
  • [50] Selective Spectrofluorimetric Protocol for Determination of Commonly Used Gram-negative Bactericidal Drug in Combined Pharmaceutical Dosage Forms and Human Plasma
    Attia, Tamer Z.
    Abdelmajed, Mahmoud A.
    Omar, Mahmoud A.
    El-Din, Khalid M. Badr
    JOURNAL OF FLUORESCENCE, 2022, 32 (02) : 603 - 612