Spectrofluorimetric determination of phenyl-β-naphthylamine used as rubber antioxidant

被引:0
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作者
Zenovia Moldovan
Cristina Stoica
Mihaela Hillebrand
Laurenţia Alexandrescu
Gabriela Macovescu
机构
[1] University of Bucharest,Faculty of Chemistry
[2] Research Development National Institute for Textile and Leather,Division Leather and Footwear Research Institute
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关键词
Phenyl-; -naphthylamine; Antioxidant; Polymer additive; Fluorimetry;
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摘要
Phenyl-β-naphthylamine (PBN) used as rubber antioxidant was found to have native fluorescence. A spectrofluorimetric method for determination of PBN in multicomponent mixtures of polymer additives is described. The apparent excitation and fluorescence wavelengths used are 348 and 413.5 nm, respectively. Maximum fluorescence intensity is obtained by irradiating PBN dissolved in ethanol, at room temperature. The fluorescence varies linearly with the concentration of PBN in the range of 0.04–4 μg mL−1. The accuracy and precision of the method are reported.
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页码:1381 / 1386
页数:5
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