Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

被引：0

作者：

Kumar S. ^{[1
]}

Patel R.N. ^{[1
]}

Khadikar P.V. ^{[1
]}

Pandeya K.B. ^{[1
,2
]}

机构：

[1] Department of Chemistry, APS University

[2] CSJM University

来源：

Journal of Chemical Sciences | 2001年 / 113卷 / 1期

关键词：

2-Ethylimidazolate-bridged; Anti-ferromagnetic interactions; Homo/hetero-binuclear complexes;

D O I：

10.1007/BF02708548

中图分类号：

学科分类号：

摘要：

Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying pH values suggest that the imidazolate-bridged complex is stable over the pH-range 7.15-10.0.

引用

页码：21 / 27

页数：6

共 50 条

[21] Equilibria and tyrosinase activity of a dinuclear and its analogous tetranuclear imidazolate-bridged copper(II) complexes
Alves, WA
Bagatin, IA
Ferreira, AMD
INORGANICA CHIMICA ACTA, 2001, 321 (1-2) : 11 - 21
[22] Structures and magnetic properties of three compounds from imidazolate-bridged copper(II) pyrazolylborate complexes
Kogane, Tamizo
Kanetomo, Takuya
Muroyama, Hiroki
Ishida, Takayuki
POLYHEDRON, 2015, 89 : 149 - 154
[23] COPPER(II) AND ZINC(II) COMPLEXES OF BETAXOLOL IN METHANOLIC SOLUTION
SPIEGLER, C
SPIESS, B
GOETZGRANDMONT, GJ
POVEY, DC
INORGANICA CHIMICA ACTA, 1992, 196 (02) : 171 - 175
[24] MAGNETIC EXCHANGE INTERACTIONS IN IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES
KOLKS, G
LIPPARD, SJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) : 5804 - 5806
[25] SYNTHESIS, STRUCTURE, AND PROPERTIES OF AN IMIDAZOLATE-BRIDGED COPPER(II)-COBALT(III) COMPLEX
DAVIS, WM
DEWAN, JC
LIPPARD, SJ
INORGANIC CHEMISTRY, 1981, 20 (09) : 2928 - 2932
[26] Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups
Zhan, SZ
Dai, Q
Yuan, CW
TRANSITION METAL CHEMISTRY, 1999, 24 (01) : 74 - 76
[27] Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups
Transition Met Chem, 1 (74-76):
[28] Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups
Shu-zhong Zhan
Qing Dai
Chun-wei Yuan
Transition Metal Chemistry, 1999, 24 : 74 - 76
[29] COPPER(II) AND ZINC(II) COMPLEXES WITH LUTIDINES
MOHAPATR.BK
RAO, DVR
INDIAN JOURNAL OF CHEMISTRY, 1970, 8 (06): : 564 - &
[30] SPECTRAL STUDIES OF COBALT(II), NICKEL(II) AND COPPER(II) COMPLEXES OF SEMICARBAZONES
SINGH, M
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1986, 16 (07): : 915 - 929

← 1 2 3 4 5 →