Synthesis and Features of Crystal Structure of Scandium Hexa(isothiocyanato)chromate(III) Complex with Nicotinic Acid

被引：0
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作者：
E. V. Cherkasova
N. V. Pervukhina
N. V. Kuratieva
T. G. Cherkasova
机构：
[1] Kuzbass State Technical University,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Russian Academy of Sciences,undefined
[3] Novosibirsk State University,undefined
来源：
Russian Journal of Inorganic Chemistry | 2018年 / 63卷
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摘要：
A double complex compound with a polymeric cation of composition [Sc2(C6H5NO2)3(C6H4NO2)3][Cr(NCS)6] has been synthesized by the reaction between Sc(NO3)3, K3[Cr(NCS)6], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals are hexagonal, space group P6322, Z = 2; a = 12.995(2) Å, c = 17.864(3) Å, V = 2612.3(7) Å3, ρcalc = 1.559 g/cm3.
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页码：776 / 780
页数：4
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