The thermodynamic characteristics of sublimation of chromium trichloride

被引：0
|
作者：
V. A. Titov
E. E. Grinberg
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
[2] Research Institute of Chemical Reagents and Special-Purity Substances,undefined
来源：
Russian Journal of Physical Chemistry | 2006年 / 80卷
关键词：
Entropy; Physical Chemistry; Chromium; Enthalpy; Chlorine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The sublimation of stoichiometric chromium trichloride was experimentally studied by the static method of vapor pressure measurements. The main reaction was found to be CrCl3(cr) = CrCl3(g). The enthalpy and entropy of this reaction were calculated. Sublimation was also performed in the presence of excess chlorine. The thermodynamic characteristics of the reaction 2CrCl3(g) + Cl2 = 2CrCl4(g) were estimated.
引用
收藏
页码：689 / 692
页数：3
相关论文
共 50 条
  • [41] STUDY OF GRAPHITE-TRICHLORIDE CHROMIUM COMPLEXES
    VANGELISTI, R
    FURDIN, G
    CARTON, B
    HEROLD, A
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1974, 278 (12): : 869 - 872
  • [42] NITRIDATION REACTION OF CHROMIUM TRICHLORIDE IN PRESENCE OF ALUMINUM
    MORI, T
    OISHI, Y
    KAWAKAMI, N
    MITAMURA, T
    MATSUDA, T
    DENKI KAGAKU, 1977, 45 (07): : 489 - 490
  • [43] The structure of Chromium Trichloride CrCl3.
    Wooster, N
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1930, 74 (3/4): : 363 - 374
  • [44] EQUILIBRIUM SUBLIMATION AND THERMODYNAMIC PROPERTIES OF SNS
    WIEDEMEIER, H
    CSILLAG, FJ
    THERMOCHIMICA ACTA, 1979, 34 (02) : 257 - 265
  • [45] THERMODYNAMIC STUDY OF SUBLIMATION OF SELENIUM OXIDE
    PIACENTE, V
    MALASPIN.L
    BARDI, G
    REVUE INTERNATIONALE DES HAUTES TEMPERATURES ET DES REFRACTAIRES, 1969, 6 (01): : 25 - &
  • [46] THE ENTHALPY OF SUBLIMATION AND THERMODYNAMIC FUNCTIONS OF FERMIUM
    HAIRE, RG
    GIBSON, JK
    JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (11): : 7085 - 7096
  • [47] THERMODYNAMIC INVESTIGATION OF SUBLIMATION OF SELENIUM DIOXIDE
    SONIN, VI
    NOVIKOV, GI
    POLYACHE.OG
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1969, 43 (11): : 1680 - &
  • [48] Torsion Vapor Pressures and Sublimation Enthalpies of Aluminum Trifluoride and Aluminum Trichloride
    Brunetti, Bruno
    Piacente, Vincenzo
    Scardala, Paolo
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (03): : 940 - 944
  • [49] THERMODYNAMICS OF THE TITANIUM CHLORIDES .3. THE SUBLIMATION PRESSURE OF TITANIUM TRICHLORIDE
    SANDERSON, BS
    MACWOOD, GE
    JOURNAL OF PHYSICAL CHEMISTRY, 1956, 60 (03): : 314 - 316
  • [50] SUBLIMATION + THERMODYNAMIC PROPERTIES OF ZINC OXIDE
    ANTHROP, DF
    SEARCY, AW
    JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (08): : 2335 - +
12345