Poly(o-bromophenol-co-N-methylaniline) [poly(OBP-co-NMA)] was electropolymerized in an acidic medium at 30°C under inert atmosphere. The formed polymer was characterized using IR spectroscopy, XRD, SEM and TGA analysis. The efficiency of the deposited polymer as a corrosion protection coating on a mild steel electrode in an acidic medium was investigated. Corrosion and impedance measurements reveal that the prepared polymer has excellent passivation properties. The free energy of adsorption of the prepared polymer on the electrode surface was in the range of ≈ − 19.5 kJ mol−1, which reveals a physical adsorption of the inhibitor molecules on the metallic surface.
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Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, IndiaSri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, India
Jyothi, S.
Ravichandran, J.
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Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, IndiaSri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, India
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C Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, IndiaC Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India
Thirumoolan, D.
Katkar, Vikas A.
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Naval Mat Res Lab, Protect Technol Div, Addl Ambernath E 421506, IndiaC Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India
Katkar, Vikas A.
Gunasekaran, G.
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Naval Mat Res Lab, Protect Technol Div, Addl Ambernath E 421506, IndiaC Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India
Gunasekaran, G.
Kanai, Tapan
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Naval Mat Res Lab, Protect Technol Div, Addl Ambernath E 421506, IndiaC Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India
Kanai, Tapan
Basha, K. Anver
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C Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, IndiaC Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India