Investigation of a non-noble composite catalyst for hydrogen release control of ammonia-borane

被引:0
|
作者
Joon-hyun Park
Han-Sung Kim
Hyun-Jong Kim
Myung-Keun Han
Yong-Gun Shul
机构
[1] Yonsei University,Department of Chemical Engineering
[2] Korea Institute of Industrial Technology,Nano Surface Technology
来源
Research on Chemical Intermediates | 2008年 / 34卷
关键词
Ammonia-borane; metal composite; catalyst; fuel cell; combinatorial method;
D O I
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中图分类号
学科分类号
摘要
Ammonia-borane (NH3BH3) has been investigated as hydrogen storage material for fuelcell application because of its good gravimetric (19.6 wt%) and volumetric hydrogen density. Nonnoble metals such as cobalt, nickel and copper were employed as catalyst and their combination was also tried as catalysts. For the effective scanning method for a number of compositions, a high throughput screening (HTS) test was used. Among the catalysts investigated, the ternary composite Ni60Co20/ACF (active carbon fiber) showed excellent performance in releasing the hydrogen from NH3BH3 solution, which can be recommended as a viable/suitable catalyst for fuel-cell system application, with some necessary basic improvements.
引用
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页码:709 / 715
页数:6
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