Molar heat capacity and thermodynamic properties of crystalline Eu(C2H5O2N)2Cl3·3H2O

被引:0
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作者
X.-C. Lv
Z.-C. Tan
X.-H. Gao
L.-X. Sun
机构
[1] Liaoning Shihua University,School of Chemistry and Material Science
[2] Dalian Institute of Chemical Physics,Division of Energy Storage, Dalian National Laboratory for Clean Energy Laboratory
[3] Chinese Academy of Sciences,Thermochemistry Laboratory
[4] Dalian Institute of Chemical Physics,Materials and Thermochemistry Laboratory
[5] Chinese Academy of Sciences,undefined
[6] Dalian Institute of Chemical Physics,undefined
[7] Chinese Academy of Sciences,undefined
关键词
Eu(C; H; O; N); Cl; ·3H; O; Adiabatic calorimetry; Low-temperature heat capacity; Thermal analysis;
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学科分类号
摘要
A complex of europium hydrochloric acid coordinated with 2-aminoacetic acid (C2H5O2N), Eu(C2H5O2N)2Cl3·3H2O was synthesized and characterized by IR and elements analysis. The heat capacities of the complex was measured with an automatic adiabatic calorimeter, and the thermodynamic functions [HT − H298.15] and [ST − S298.15] were derived in the temperature range from 80 to 340 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scan calorimeter (DSC).
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页码:971 / 976
页数:5
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