Synthesis and Crystal Structure of the Octametallic Ferrocene Containing Molybdenum(V) Cluster Mo4(μ3-O)4(μ2-O2P(CH2)2Fc)4O4 and Crystal Structure of 1,1′-Bis(Chloromethyl)Ferrocene

被引：0
|
作者：
John S. Maass
Matthias Zeller
Rudy L. Luck
机构：
[1] Michigan Technological University,Department of Chemistry
[2] Youngstown State University,Department of Chemistry
来源：
Journal of Cluster Science | 2012年 / 23卷
关键词：
Molybdenum tetramer; Distorted cube; Organophosphinic acid; X-ray diffraction; Ferrocene;
D O I：
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摘要：
The reaction of MoO2(acac)2 with 1,1′-[phosphinicobis(methylene)]-ferrocene in ethanol at 120 °C and in the presence of triethylamine results in the octametallic cluster Mo4(μ3-O)4(μ2-O2P(CH2)2Fc)4O4. If the reaction is carried out in the absence of triethylamine a mixture of products are obtained of which the identity of the compound produced was hypothesized but not definitively established. Mo4(μ3-O)4(μ2-O2P(CH2)2Fc)4O4 is characterized by IR and 31P-NMR spectroscopy along with the single crystal X-ray determination of its structure. The crystal structure of 1,1′-bis(chloromethyl)ferrocene is also detailed.
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页码：713 / 726
页数：13
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