Crystal structure of copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide

被引：0
|
作者：
V. Yu. Gusev
D. A. Muksinova
P. A. Slepukhin
A. V. Radushev
机构：
[1] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
[2] Russian Academy of Sciences,Postovsky Institute of Organic Synthesis, Ural Branch
来源：
Russian Journal of Coordination Chemistry | 2012年 / 38卷
关键词：
Benzoic Acid; Tert; Tert Butyl Group; Metal Ring; Donor Acceptor Bond;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
X-Ray diffraction analysis was performed for the copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide, Cu(p-(tert-Bu)C6H4CONHNMe2)2 (I). The reagent functions as a bidentate (O,N(2)) ligand giving a five-membered copper-containing ring. The molecule is centrosymmetric. The Cu atom and the metal rings lie in the same plane. The coordination polyhedron of copper is a slightly distorted square. The crystals are monoclinic: a = 16.2634(14) Å, b = 9.0415(8) Å, c = 9.6415(9) Å, α = 90°, β = 100.052(7)°, Z = 2, space group P21/c.
引用
收藏
页码：515 / 518
页数：3
相关论文
共 50 条
  • [31] Synthesis and Crystal Structure of 4-(tert-butyl)-N-(pyridin-3-ylmethyl) benzenesulfonamide
    K. Balu
    R. Srinivasa Gopalan
    Journal of Chemical Crystallography, 2013, 43 : 409 - 411
  • [32] CRYSTAL AND MOLECULAR-STRUCTURE OF BINUCLEAR COPPER(II) CHELATE OF N-2,3-DIMETHYLPHENYLANTRANILIC ACID AND DIMETHYLFORMAMIDE
    GLOWIAK, T
    MYSKIV, MG
    JEZOWSKATRZEBIATOWSKA, B
    YATSYMIRSKY, KB
    HLADYSHEVSKY, EI
    KRYSS, EE
    GRYGORIEVA, AS
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1978, 34 : S142 - S143
  • [33] REACTIONS OF SOME METAL CHLORIDES WITH N,N-BIS(TRIMETHYLSILYL) AMIDO N (TERT-BUTYL)IMIDOTHIOPHOSPHENIC ACID
    BRUSILOVETS, AI
    TRACHEVSKY, VV
    KOLESNICHENKO, VI
    DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1990, (09): : 33 - 35
  • [34] Synthesis, crystal structure, thermal studies and antimicrobial activity of a new chelate complex of copper(II) succinate with N,N,N′,N′-tetramethylethylenediamine
    Batool, Syeda Shahzadi
    Gilani, Syeda Rubina
    Zainab, Syeda Sakina
    Tahir, Muhammad Nawaz
    Harrison, William T. A.
    Haider, Muhammad Salman
    Syed, Quratulain
    Mazhar, Sania
    Shoaib, Muhammad
    JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (12) : 1778 - 1789
  • [35] CRYSTAL-STRUCTURE OF BINUCLEAR COPPER(II) CHELATE OF "N-3-HYDROXYPROPYL-SALICYLIDENEIMINE
    OGAWA, K
    TAMURA, H
    ACTA CRYSTALLOGRAPHICA SECTION A, 1972, 28 : S87 - S87
  • [36] Crystal structure of tert-butyl-N-phenyl-carbonitrilium tetrachloridoaluminate
    van Dijk, Tom
    Zant, Dirk W.
    Wolf, Robert
    Lammertsma, Koop
    Slootweg, J. Chris
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 331 - +
  • [37] CRYSTAL STRUCTURE OF COPPER(2) CHELATE OF N,N'-ETHYLENEBIS(L-EPHEDRINE)
    MOTOHASHI, M
    AMANO, Y
    UNO, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (09) : 2007 - +
  • [38] CRYSTAL-STRUCTURE OF A MESOGENIC COPPER(II) SQUARE-PLANAR COMPLEX BIS[N-PARA-(NORMAL-HEXYLOXY)PHENYL,PARA-(NORMAL-HEPTYLOXY)SALICYLALDIMINATO] COPPER(II)
    ROVIELLO, A
    SIRIGU, A
    IANNELLI, P
    IMMIRZI, A
    LIQUID CRYSTALS, 1988, 3 (01) : 115 - 122
  • [39] SULTAMS .14. DIETHYLAMINOETHYL ESTER OF PARA-(N-BUTANESULTAMYL-1,4)BENZOIC ACID
    HELFERICH, B
    ZEID, I
    JOURNAL FUR PRAKTISCHE CHEMIE-PRACTICAL APPLICATIONS AND APPLIED CHEMISTRY, 1969, 311 (01): : 172 - +
  • [40] Synthesis and crystal structure of N-tert-butyl-N′-thio [O-(1-methylthioethylimino)-N″-methylcarbamic acid]-N,N′-dibenzoylhydrazine
    Shang Jian
    Wang Qing Min
    Huang Run Qiu
    Mao Chun Hui
    Chen Li
    Song Hai Bin
    Journal of Chemical Crystallography, 2005, 35 : 147 - 150
12345