Formation of a six-coordinate fac-[Re(CO)3]+ complex by the N-C bond cleavage of a potentially tetradentate ligand

被引：0

作者：

I. Booysen

T. I. A. Gerber

E. Hosten

P. Mayer

机构：

[1] Nelson Mandela Metropolitan University,Department of Chemistry

[2] Ludwig-Maximilians University,Department of Chemistry

来源：

Journal of the Iranian Chemical Society | 2008年 / 5卷

关键词：

Rhenium(I); Cleavage of N-C bond; Diaminoamide; Crystal structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The rhenium(I) compound fac-[Re(CO)3(daa)].Hpab.H2O (Hpab = N,N’-(1,2-phenylene)bis(2′-aminobenzamide); Hdaa = 2- amino-N-(2-aminophenyl)benzamide) was synthesized from the reaction of [Re(CO)5Br] with two equivalent of Hpab in toluene. The monoanionic tridentate ligand daa was formed by the rhenium-mediated cleavage of an amido N-C bond of the potentially tetradentate ligand Hpab. The compound was characterized by IR spectroscopy and X-ray crystallography, and daa is coordinated as a diaminoamide via three nitrogen-donor atoms.

引用

页码：689 / 693

页数：4

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