Synthesis of carboxylic acid esters in the presence of micro- and mesoporous aluminosilicates

被引：0
|
作者：
N. G. Grigor’eva
A. M. Suleimanova
M. R. Agliullin
B. I. Kutepov
机构：
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源：
Russian Journal of Applied Chemistry | 2014年 / 87卷
关键词：
Zeolite; Zeolitic Catalyst; Caproic Acid; Strong Acid Site; Monocarboxylic Acid;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The catalytic properties of zeolites HY, HBeta, and HZSM-12 and of mesoporous amorphous aluminosilicate in liquid-phase esterification of aliphatic (monobasic C1–C18, dibasic C6, C10) and aromatic (benzoic, trimellitic, phthalic) carboxylic acids with butanol were studied. Zeolite HBeta appeared to be the most active catalyst. Procedures were developed for preparing esters in the presence of zeolitic catalyst HBeta, ensuring 100% selectivity of ester formation at 90–98% conversion of the acid.
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页码：773 / 779
页数：6
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