The effect of poly(methacrylic acid) on electrosurface properties of titanium dioxide in aqueous suspensions

被引:0
|
作者
R. S. Petryshyn
Z. M. Yaremko
M. N. Soltys
机构
[1] Ivan Franko National University of Lviv,
来源
Colloid Journal | 2013年 / 75卷
关键词
Adsorption Layer; Colloid Journal; Methacrylic Acid; PMAA; Ionization Constant;
D O I
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中图分类号
学科分类号
摘要
The electrosurface properties and aggregation stability of aqueous titanium-dioxide suspensions are studied in wide ranges of medium pH values and poly(methacrylic acid) concentrations. Using the 2pK model, the ionization constants of surface hydroxyl groups of titanium dioxide are found and it is established that the adsorption of poly(methacrylic acid) macromolecules substantially decreases the fraction of neutral (uncharged) hydroxyl groups and affects the ratio between the positively and negatively charged surface hydroxyl groups.
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页码:698 / 705
页数:7
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