Characterization and reactivity of aerogel sulfated zirconia-ceria catalyst for n-hexane isomerization

被引：0
|
作者：
I. Mejri
M. K. Younes
A. Ghorbel
P. Eloy
E. M. Gaigneaux
机构：
[1] Faculté des Sciences de Tunis,Laboratoire de Chimie des Matériaux et Catalyse
[2] Université Catholique de Louvain,Unité de Catalyse et Chimie des Matériaux Divisés
来源：
Journal of Porous Materials | 2010年 / 17卷
关键词：
Sol gel materials; n-hexane isomerisation; Acidity; XPS spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Sulfated zirconia doped with cerium has been prepared by sol gel process using the supercritical evacuation way of the solvent. The physicochemical and catalytic properties of aerogel solids AZC were compared as a function of both the Ce/Zr molar ratio and the calcination temperature. The samples were characterized by N2 adsorption desorption, XRD, FTIR, RAMAN, XPS spectroscopy and TPD of NH3. The catalyst prepared with molar ratio Ce/Zr = 0.4 exhibits the high activity and selectivity toward isomerization product in the n-hexane isomerization reaction. This result is probably due to its important total acidity.
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页码：545 / 551
页数：6
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