Cleavage of the cyclic substituent in the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions upon the interaction with negatively charged N-nucleophiles

被引：0

作者：

E. Yu. Matveev

V. M. Retivov

G. A. Razgonyaeva

K. Yu. Zhizhin

N. T. Kuznetsov

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

[2] Lomonosov State Academy of Fine Chemical Technology,undefined

来源：

Russian Journal of Inorganic Chemistry | 2011年 / 56卷

关键词：

Boron Neutron Capture Therapy; Anionic Part; Tetraphenylphosphonium; Cationic Part; Viscous Substance;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The interaction of the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions with negatively charged N-nucleophiles has been studied. It has been shown that such reactions yield doubly charged substituted closo-decaborates with a nitrogen-containing group attached to the cluster through an alkoxyl spacer. Compounds with pendant NO2−, N3−, N(CO)2C6H4−, and NHC6H5 groups have been synthesized.

引用

页码：1549 / 1554

页数：5

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