Synthesis and crystal structure of new one-dimensional copper(II) complex [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2]n

被引：0

作者：

A. D. Khalaji

H. Stoeckli-Evans

机构：

[1] Golestan University,Department of Chemistry, Faculty of Science

[2] University of Neuchatel,Institute of Physics, Laboratory Physical Chemistry

来源：

Russian Journal of Coordination Chemistry | 2011年 / 37卷

关键词：

Azido; Apical Plane; Tetranuclear Cluster; Azido Ligand; Azido Bridge;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new polymer azido-bridged copper(II) complex [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2]n (I) (En = ethylenediamine) has been synthesized and crystallography characterized. Complex I shows one-dimensional coordination polymeric structure based on a tetranuclear cluster unit [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2], in which the azido ions display three different bridging modes.

引用

页码：535 / 540

页数：5

共 50 条

[1] Synthesis and crystal structure of new one-dimensional copper(II) complex [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2] n
Khalaji, A. D.
Stoeckli-Evans, H.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (07) : 535 - 540
[2] Synthesis, characterization and crystal structure of tetranuclear copper(II) complex [Cu4(μ-Salophen)2(μ1,1-N3)2(N3)2] with alternating μ1,1-azido and phenoxo bridges
A. D. Khalaji
S. Triki
Russian Journal of Coordination Chemistry, 2012, 38 : 579 - 582
[3] Synthesis, characterization and crystal structure of tetranuclear copper(II) complex [Cu4(μ-Salophen)2(μ1,1-N3)2(N3)2] with alternating μ1,1-azido and phenoxo bridges
Khalaji, A. D.
Triki, S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (08) : 579 - 582
[4] Structure and magnetic behaviour of [{Mn2(3-Et,4-Mepy)6(μ1,1-N3)2(μ1,3-N3)}n][PF6]n and [{Mn2(3-ampy)4(μ1,1-N3)2(μ1,3-N3)(N3)(H2O)• 4H2O}n], two alternating ferro-antiferromagnetic one-dimensional compounds
Abu Youssef, M
Escuer, A
Goher, MAS
Mautner, FA
Vicente, R
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (03): : 413 - 416
[5] A novel tetranuclear copper(II) complex with alternating μ1,1-azido and phenoxo bridges:: Synthesis, structure, and magnetic properties of [Cu4(μ-salen)2(μ1,1-N3)2(N3)2]
Koner, S
Saha, S
Okamoto, KI
Tuchagues, JP
INORGANIC CHEMISTRY, 2003, 42 (15) : 4668 - 4672
[6] Structure and magnetic behaviour of the one-dimensional [{Ni2(Medien)2(μ1,1-N3)2(μ1,3-N3)}n][ClO4]n compound with unusually strong ferro-antiferromagnetic alternating interactions
Escuer, A
Vicente, R
El Fallah, MS
Kumar, SB
Mautner, FA
Gatteschi, D
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (23): : 3905 - 3909
[7] A one-dimensional copper(II) coordination polymer [Cu3(ampym)2(μ1,1-N3)4(μ1,3-N3)2(dmf)2]n (ampym=2-aminopyrimidine) containing both end-on and end-to-end azido bridges
Song, YF
Massera, C
Quesada, M
Lanfredi, AMM
Mutikainen, P
Turpeinen, U
Reedijk, J
INORGANICA CHIMICA ACTA, 2005, 358 (04) : 1171 - 1178
[8] Tetranuclear azido-bridged copper(II) complex [Cu4(μ-salpn)2(μ1,1-N3)2(N3)2-(H2O)2]: Synthesis, characterization and crystal structure
Khalaji, Aliakbar Dehno
Stoekh-Evans, Helen
POLYHEDRON, 2009, 28 (17) : 3769 - 3773
[9] Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M = Ni, Co, Cd) complexes
Mautner, Franz A.
Scherzer, Michael
Berger, Christian
Fischer, Roland C.
Vicente, Ramon
Massoud, Salah S.
POLYHEDRON, 2015, 85 : 329 - 336
[10] Three new dinuclear copper(II) complexes with [Cu(μ1,3-N3)2Cu]2+ and [Cu(μ1,1-N3)2Cu]2+ asymmetrical cores:: syntheses, structures and magnetic behaviour
Escuer, A
Font-Bardía, M
Massoud, SS
Mautner, FA
Peñalba, E
Solans, X
Vicente, R
NEW JOURNAL OF CHEMISTRY, 2004, 28 (06) : 681 - 686

← 1 2 3 4 5 →