Features of Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with 1,2-Dicarbonyl Compounds

被引：0

作者：

V. F. Mironov

G. A. Ivkova

L. M. Abdrakhmanova

E. V. Mironova

R. Z. Musin

V. K. Cherkasov

机构：

[1] Kazan Scientific Center of the Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry

[2] Kazan (Volga Region) Federal University,Razuvaev Institute of Organometallic Chemistry

[3] Russian Academy of Sciences,undefined

来源：

Russian Journal of General Chemistry | 2018年 / 88卷

关键词：

diazaphosphol; tetrachloro-1,2-benzoquinone; phenanthrenequinone; perfluorodiacetyl; phosphorane;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one reacts with perfluorodiacetyl, 3,6-di(tert-butyl)-1,2-benzoquinone and phenanthrenequinone only with the participation of a three-coordinated phosphorus atom to form spirophosphoranes containing acyclic 5-methyl-2- phenyl-2H-1,2,3-diazaphosphol-4-yl substituent, whereas the interaction with tetrachloro-1,2-benzoquinone proceeds via expanding the six-membered heterocycle to the nine-membered one to form 2-(2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-2,9-dioxo-4,5,6,7-tetrachlorodibenzo[d,h]-1,3,8-trioxaphosphonine.

引用

页码：430 / 438

页数：8

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