Features of Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with 1,2-Dicarbonyl Compounds

被引：0
|
作者：
V. F. Mironov
G. A. Ivkova
L. M. Abdrakhmanova
E. V. Mironova
R. Z. Musin
V. K. Cherkasov
机构：
[1] Kazan Scientific Center of the Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry
[2] Kazan (Volga Region) Federal University,Razuvaev Institute of Organometallic Chemistry
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of General Chemistry | 2018年 / 88卷
关键词：
diazaphosphol; tetrachloro-1,2-benzoquinone; phenanthrenequinone; perfluorodiacetyl; phosphorane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one reacts with perfluorodiacetyl, 3,6-di(tert-butyl)-1,2-benzoquinone and phenanthrenequinone only with the participation of a three-coordinated phosphorus atom to form spirophosphoranes containing acyclic 5-methyl-2- phenyl-2H-1,2,3-diazaphosphol-4-yl substituent, whereas the interaction with tetrachloro-1,2-benzoquinone proceeds via expanding the six-membered heterocycle to the nine-membered one to form 2-(2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-2,9-dioxo-4,5,6,7-tetrachlorodibenzo[d,h]-1,3,8-trioxaphosphonine.
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页码：430 / 438
页数：8
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