Synthesis of amino-containing meso-aryl-substituted porphyrins and their conjugates with the closo-decaborate anion

被引:0
|
作者
K. A. Zhdanova
A. P. Zhdanov
A. V. Ezhov
N. A. Bragina
K. Yu. Zhizhin
I. P. Ushakova
A. F. Mironov
N. T. Kuznetsov
机构
[1] M. V. Lomonosov Moscow State University of Fine Chemical Technologies,N. S. Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,undefined
来源
Russian Chemical Bulletin | 2014年 / 63卷
关键词
macrocyclic compounds; -aryl-substituted porphyrins; aminoporphyrins; -decaborate anion; addition to nitrogen-carbon multiple bonds;
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学科分类号
摘要
Amphiphilic meso-aryl-substituted porphyrins containing an amino group and long-chain hydrophobic substituents were synthesized. Two strategies of the synthesis of asymmetric amino-containing porphyrins using p-acetamidobenzaldehyde and p-nitrobenzaldehyde were developed and investigated. A series of new substituted porphyrin-containing closo-decaborates were prepared based on the synthesized porphyrins and nitrilium derivatives of the closo-decaborate anion [B10H10]2−.
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页码:194 / 200
页数:6
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