Structure of the key species in the enzymatic oxidation of methane to methanol

被引：0
|
作者：
Rahul Banerjee
Yegor Proshlyakov
John D. Lipscomb
Denis A. Proshlyakov
机构：
[1] Molecular Biology & Biophysics,Department of Biochemistry
[2] University of Minnesota,Department of Chemistry
[3] Center for Metals in Biocatalysis,undefined
[4] University of Minnesota,undefined
[5] Michigan State University,undefined
来源：
Nature | 2015年 / 518卷
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摘要：
Time-resolved resonance Raman vibrational spectroscopy was used to study the mechanism of soluble methane monooxygenase and obtain structural information on the key reaction cycle intermediate, compound Q, which contains a unique dinuclear FeIV cluster that breaks the strong C-H bond of methane and inserts an oxygen atom (from O2) to form methanol.
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页码：431 / 434
页数：3
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