Structure and Magnetic Properties of a 3d–4f-Doped Hexagonal Heterometallic Cluster

被引：0

作者：

Qi-Zhen Yang

Min-Jia Zheng

Hua-Hong Zou

Hai-Ling Wang

Dong-Cheng Liu

Yan-Cheng Liu

Fu-Pei Liang

机构：

[1] Guangxi Normal University,State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy

[2] Guilin University of Technology,Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering

来源：

Journal of Cluster Science | 2019年 / 30卷

关键词：

Hexanuclear cluster; Heterometallic; Crystal structure; Magnetic properties;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

2-(2,3-Dihydroxpropyliminomethyl)6-methoxyphenol (H3L), trimethylacetic acid (Hpiv), Dy(NO3)3·6H2O and Co(NO3)2·6H2O were reacted at 80 °C to obtain a heterometallic hexanuclear cluster [Dy2Co4(L)2(μ3-OH)2(piv)8]·2Hpiv·2H2O (1). X-ray crystallographic study reveals that complex 1 displays a central planar butterfly motif consisting of the Dy2IIICo2II, with another two CoII ions ‘‘capping’’ around the periphery of the butterfly. Magnetic studies suggest that 1 displays little out-of-phase component of the ac-susceptibilities in zero dc-field, and observed weak imaginary component.

引用

页码：25 / 30

页数：5

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