Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

被引：0
|
作者：
SAGAR SHARMA
TAPASH CHAKRABORTY
KRITI SRIVASTAVA
HARKESH B SINGH
机构：
[1] Indian Institute of Technology Bombay,Department of Chemistry
来源：
Journal of Chemical Sciences | 2011年 / 123卷
关键词：
M–C bond cleavage; metallophilic; secondary bonding intramolecular interaction; organochalcogen; telluroxane; transmetallation.;
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暂无
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学科分类号：
摘要：
Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal–metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen–carbon bonds.
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页码：113 / 122
页数：9
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