[M(NH3)5Cl]WO4 (M = Cr, Rh): Synthesis, crystal structure, thermal properties

被引：0
|
作者：
S. A. Gromilov
S. P. Khranenko
P. E. Plyusnin
P. Yu. Vanina
N. V. Kuratieva
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,Scientific and Educational Complex “Nanosystems and Advanced Materials,”
来源：
Journal of Structural Chemistry | 2013年 / 54卷
关键词：
tungsten; rhodium; chrome; complex salt; crystal chemistry; single crystal X-ray diffraction study; thermal properties;
D O I：
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中图分类号：
学科分类号：
摘要：
By single crystal X-ray diffraction the crystal structure of a series of [M(NH3)5Cl]WO4 (M = Cr, Rh) complex salts is determined. The features of thermal expansion of the single crystal of [Cr(NH3)5Cl]WO4 are studied by low- and high-temperature X-ray diffractometry in the temperature range from −173°C to +127°C. It is shown that with an increase in the temperature, W-O distances and ∠O-W-O bond angles equalize and the average W-O distances decrease by 0.012 Å. The thermal properties of the salts in different gaseous atmospheres are examined and the phase composition of the obtained products is studied.
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页码：1077 / 1082
页数：5
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