Single-stage synthesis of phosphazene-containing epoxy oligomers

被引：0
|
作者：
I. S. Sirotin
Yu. V. Bilichenko
K. A. Brigadnov
V. V. Kireev
B. M. Prudskov
R. S. Borisov
机构：
[1] Mendeleev University of Chemical Technology,Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,undefined
来源：
Polymer Science Series B | 2014年 / 56卷
关键词：
Polymer Science Series; Epichlorohydrin; Phosphazene; Epoxy Oligomer; Laser Mass Spectrometry;
D O I：
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学科分类号：
摘要：
A single-stage synthesis of phosphazene-containing epoxy oligomers via the direct interaction of hexachlorocyclotriphosphazene, diphenylolpropane and epichlorohydrin has been proposed. The resulting products are composed of a common epoxy-diane oligomer and an epoxyphosphazene component, with the content of the latter being up to 45 wt %. Oligomers with epoxy numbers up to 22 were characterized with the use of gel permeation chromatography, chromatography-mass spectrometry, laser mass spectrometry, 31P NMR spectroscopy, and 1H NMR spectroscopy.
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页码：471 / 476
页数：5
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