Single-Stage Synthesis of Phosphazene-Containing Epoxy Oligomers

被引：15
|
作者：
Sirotin, I. S. [1 ]
Bilichenko, Yu. V. [1 ]
Brigadnov, K. A. [1 ]
Kireev, V. V. [1 ]
Prudskov, B. M. [1 ]
Borisov, R. S. [2 ]
机构：
[1] Mendeleev Univ Chem Technol, Moscow 125047, Russia
[2] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
来源：
POLYMER SCIENCE SERIES B | 2014年 / 56卷 / 04期
关键词：
RESIN; DERIVATIVES;
D O I：
10.1134/S1560090414040113
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A single-stage synthesis of phosphazene-containing epoxy oligomers via the direct interaction of hexachlorocyclotriphosphazene, diphenylolpropane and epichlorohydrin has been proposed. The resulting products are composed of a common epoxy-diane oligomer and an epoxyphosphazene component, with the content of the latter being up to 45 wt %. Oligomers with epoxy numbers up to 22 were characterized with the use of gel permeation chromatography, chromatography-mass spectrometry, laser mass spectrometry, P-31 NMR spectroscopy, and H-1 NMR spectroscopy.
引用
收藏
页码：471 / 476
页数：6
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