Crystal structure and luminescence of europium(III) acrylate

被引：0
|
作者：
B. V. Bukvetskii
N. V. Petrochenkova
A. G. Mirochnik
机构：
[1] Russian Academy of Sciences,Institute of Chemistry, Far East Division
[2] G. I. Nevelskii Marine State University,undefined
来源：
Journal of Structural Chemistry | 2009年 / 50卷
关键词：
crystal structure; europium(III); acrylate; luminescence;
D O I：
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中图分类号：
学科分类号：
摘要：
The atomic structure of europium acrylate crystals [Eu2(Acr)5OH·3H2O]·2(0.5H2O) was studied by X-ray analysis (a = 24.360(3) Å, b = 18.466(2) Å, c = 8.5818(9) Å, β = 96.087(2)°, space group C2/c, Z = 6, ρcalc = 2.036 g/cm3). The crystal structure involves chains of binuclear [Eu2(C3H3O2)5OH·3H2O] molecules, running infinitely in the [101] direction and having pairs of C9H9EuO7H2O molecules alternating with C6H6EuO4OH·2H2O molecules that link the pairs. The infinite chains are linked by hydrogen bonds and van der Waals interactions. The thermal behavior of luminescence of the europium(III) complex is discussed.
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页码：485 / 489
页数：4
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