The use of sulfonyl halides as initiators of cationic polymerization of oxazolines

被引：0
|
作者：
M. P. Kurlykin
A. B. Razina
A. V. Ten’kovtsev
机构：
[1] Russian Academy of Sciences,Institute of Macromolecular Compounds
[2] St. Petersburg State University,Institute of Chemistry
来源：
Polymer Science Series B | 2015年 / 57卷
关键词：
Polymer Science Series; Tosyl; Monomer Conversion; Oxazoline; Tetrachloroethane;
D O I：
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中图分类号：
学科分类号：
摘要：
The kinetic investigations of the cationic polymerization of 2-ethyl-2-oxazoline are performed with the use of aromatic sulfonic acid halides as initiators. The rate constants of chain propagation and the activation energy are calculated. It is found that the polymerization predominantly proceeds via the livingchain, rather than the pseudoliving, polymerization mechanism.
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页码：395 / 401
页数：6
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