The use of sulfonyl halides as initiators of cationic polymerization of oxazolines

被引：9
|
作者：
Kurlykin, M. P. [1 ]
Razina, A. B. [1 ]
Ten'kovtsev, A. V. [1 ,2 ]
机构：
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[2] St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia
来源：
POLYMER SCIENCE SERIES B | 2015年 / 57卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
2-PHENYL-2-OXAZOLINE; 2-ETHYL-2-OXAZOLINE; 2-OXAZOLINES;
D O I：
10.1134/S1560090415050085
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetic investigations of the cationic polymerization of 2-ethyl-2-oxazoline are performed with the use of aromatic sulfonic acid halides as initiators. The rate constants of chain propagation and the activation energy are calculated. It is found that the polymerization predominantly proceeds via the livingchain, rather than the pseudoliving, polymerization mechanism.
引用
收藏
页码：395 / 401
页数：7
相关论文
共 50 条
  • [1] The use of sulfonyl halides as initiators of cationic polymerization of oxazolines
    M. P. Kurlykin
    A. B. Razina
    A. V. Ten’kovtsev
    Polymer Science Series B, 2015, 57 : 395 - 401
  • [2] Alkylsulfonyl Halides as Initiators of Cationic Polymerization of Oxazolines
    A. N. Blokhin
    M. P. Kurlykin
    A. B. Razina
    M. M. Dudkina
    A. V. Ten’kovtsev
    Polymer Science, Series B, 2018, 60 : 421 - 426
  • [3] Alkylsulfonyl Halides as Initiators of Cationic Polymerization of Oxazolines
    Blokhin, A. N.
    Kurlykin, M. P.
    Razina, A. B.
    Dudkina, M. M.
    Ten'kovtsev, A. V.
    POLYMER SCIENCE SERIES B, 2018, 60 (04) : 421 - 426
  • [4] ORGANIC HALIDES AS CATIONIC INITIATORS
    BURGESS, FJ
    CUNLIFFE, AV
    RICHARDS, DH
    THOMPSON, D
    POLYMER, 1978, 19 (03) : 334 - 340
  • [5] Cationic ring-opening polymerization of 2-oxazolines in γ-butyrolactones using various initiators
    Chen, Tingwei
    Zhao, Chenke
    Lai, Tao
    Zhao, Junpeng
    POLYMER CHEMISTRY, 2025, 16 (07) : 903 - 912
  • [6] NOVEL MULTIFUNCTIONAL INITIATORS FOR POLYMERIZATION OF 2-OXAZOLINES
    KOBAYASHI, S
    UYAMA, H
    NARITA, Y
    ISHIYAMA, JI
    MACROMOLECULES, 1992, 25 (12) : 3232 - 3236
  • [7] Systematic investigation of alkyl sulfonate initiators for the cationic ring-opening polymerization of 2-oxazolines revealing optimal combinations of monomers and initiators
    Glassner, Mathias
    D'hooge, Dagmar R.
    Park, Jin Young
    Van Steenberge, Paul H. M.
    Monnery, Bryn D.
    Reyniers, Marie-Francoise
    Hoogenboom, Richard
    EUROPEAN POLYMER JOURNAL, 2015, 65 : 298 - 304
  • [8] Tetrafunctional initiators for cationic polymerization of olefins
    Taylor, SJ
    Storey, RF
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (23) : 5942 - 5953
  • [9] TRIALKYLSILYL TRIFLATES, NOVEL INITIATORS FOR CATIONIC POLYMERIZATION
    GONG, MS
    HALL, HK
    MACROMOLECULES, 1986, 19 (12) : 3011 - 3012
  • [10] NOVEL INITIATORS HAVING ACETYLENE GROUP FOR POLYMERIZATION OF 2-OXAZOLINES
    KOBAYASHI, S
    UYAMA, H
    MORI, T
    NARITA, Y
    CHEMISTRY LETTERS, 1991, (10) : 1771 - 1774
12345