Molecular structure and conformation study of p-[N,N-bis(2-Chloroethyl)amino] benzaldehyde-4-phenyl thiosemicarbazone

被引：0
|
作者：
S. Anitha
J. Karthikeyan
A. Nityananda Shetty
机构：
[1] Sathyabama University,Department of Chemistry
[2] National Institute of Technology Karnataka,Department of Chemistry
来源：
Journal of Structural Chemistry | 2012年 / 53卷
关键词：
phenyl thiosemicarbazone; thiosemicarbazone; -[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-phenyl thiosemicarbazone; spectral studies;
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摘要：
The crystal structure of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-phenyl thiosemicarbazone(CEAB-4-PTSC) is described. The compound crystallizes in the monoclinic crystal system, P21/c space group, Z = 4, calculated density = 1.327 mg/cm3, V = 1978.2(6) Å3 with unit cell parameters a = 16.240(3) Å, b = 12.821(2) Å, c = 9.8543(16) Å, β = 105.382(6)°. The crystal structure reveals that the compound exists in the thione form and S1 and N2 are at trans-conformation to each other with respect to the N3-C12 bond. The packing of molecules in the crystal lattice is stabilized by intramolecular hydrogen bonds.
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页码：932 / 937
页数：5
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