Onium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and Aniline

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作者
R. E. Khoma
V. O. Gel’mbol’dt
A. A. Ennan
V. N. Baumer
I. M. Rakipov
R. M. Dlubovskii
机构
[1] MES and NAS of Ukraine,Physical Chemical Institute for Environment and Human Protection
[2] Odessa Mechnikov National University,NTK Institute of Single Crystals
[3] Odessa National Medical University,Bogatsky Physico
[4] National Academy of Sciences of Ukraine,Chemical Institute
[5] National Academy of Sciences of Ukraine,undefined
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The reaction products formed in the SO2–L–H2O–O2 systems (L is n-propylamine, n-butylamine, tert-butylamine, n-heptylamine, n-octylamine, aniline) were isolated and identified as “onium” salts [n-C3H7NH3]2SO4, [n-C4H9NH3]2SO4, [t-C4H9NH3]2SO4, [n-C7H15NH3]3SO4(HSO4), [n-C8H17NH3]3SO4(HSO4), and [C6H5NH3]2SO4. The products were characterized by elemental analysis, IR and Raman spectroscopy, mass spectrometry, and thermogravimetry.
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页码:655 / 660
页数:5
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