Fermi resonance of optical one-phonon and acoustic two-phonon vibrations in light metals

It is shown that the anharmonicity of crystal lattice vibrations in light metals such as beryllium, can give rise to a Fermi resonance of optical one-phonon and acoustic two-phonon vibrations. New hybridized vibrational states are formed as a result of such a resonance interaction: biphonon and quasibiphonon vibrations and renormalized optical vibrations. Depending on the wave vector, these vibrational states can be both damped and stationary. The corresponding dispersion equation is obtained, whose solution made it possible to determine the spectrum of these vibrations (dispersion curves and the wave vector dependence of the damping for damped vibrations). It is shown that ultrafast damping of optical vibrations, similar to the well-known superradiance effect for Frenkel’ and Wannier-Mott excitons, is possible.