Structural characteristics of gas hydrates within the framework of generalized crystallography

被引:0
|
作者
A. L. Talis
机构
[1] Russian Institute of Synthesis of Mineral Raw Materials,
来源
Crystallography Reports | 2003年 / 48卷
关键词
Hydrate; Structural Characteristic; Guest Molecule; Incidence Graph; Symmetry Level;
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中图分类号
学科分类号
摘要
It is shown that the symmetry of the {5, 3, 3} polytope (four-dimensional dodecahedron) embedded into E4 enables one to derive all the polyhedra—cavities that make up gas hydrates from the {5, 3} dodecahedron. Consideration is given to the allomorphic embedding of the {5, 3} subgraph into the incidence graph of the Desargues configuration 103, which determines the mechanism of incorporation of guest molecules into the polyhedra—cavities of gas hydrates and their escape from these polyhedra at the symmetry level. The relationships obtained may be considered as a basis for an a priori derivation of the determined (periodic and aperiodic) structures of gas hydrates.
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页码:347 / 350
页数:3
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